Product ID:S299500 SODIUM FLUORIDE,SOLID
MSDS Date:05/27/1995
FSC:6810
NIIN:00F046392
MSDS Number: BYMWY

FISHER SCIENTIFIC CHEMICAL DIV

1 REAGENT LN
FAIR LAWN, NJ 07410-2802
US

Emergency Phone: 201-796-7100/201-796-7523

Info Phone: 201-796-7100/201-796-7523

Cage: 1B464

FISHER SCIENTIFIC CO. CHEMICAL MFG DIV

FAIRLAWN, NJ 07410-2802 US

Telephone: 201-796-7100

Cage: 1B464

SODIUM FLUORIDE

CAS: 7681-49-4

RTECS: WB0350000

Fraction By Weight: 100%

OSHA PEL 2.5 MG/CUM

ACGIH TLV: 2.5 MG/CUM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:ORAL LD50(RAT): 52 MG/KG SODIUM FLUORIDE
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: CORROSIVE, SEVERE MUCOUS
MEMBRANE IRRITATION, PNEUMOCONIOSIS, RESPIRATORY DEPRESSION,
SERIOUS POISONING. SKIN: IRRITATION, CORROSION, BURNS, DERMATITIS.
EYES: SEVERE IRRITATION. INGESTION: DAMAGE TO GASTRIC MUCOSA,
COMA, CARDIOVASCULAR & RESPIRATORY FAILURE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, COUGHING, SORE THROAT, SHORTNESS OF
BREATH, HEADACHE, CYANOSIS, REDNESS, PAIN, BURNS, BLURRED VISION,
NAUSEA, VOMITING, DIARRHEA, SALIVATION, THIRST, ABDOMINAL PAIN,
PERSPIRATION, DYSPNEA, HICCUPS, CONTRACTION OF PUPILS, WEAKNESS,
TREMORS, CONVULSIONS, COLLAPSE, LOW BLOOD CALCIUM LEVELS, COMA.

First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF
NECESSARY. MAINTAIN AIRWAY, BLOOD PRESSURE & RESPIRATORY. KEEP WARM
& QUIET. TREAT SYMPTOMATICALLY & SUPPORTIVELY. SKIN: WASH
W/SOAP/MILD DETERGENT & LARGE AMOUNTS OF WATER FOR 15-20 MINS. IF
BURNS OCCUR, COVER AREA W/STERILE, DRY, LOOSE-FITTING DRESSING.
EYES: WASH W/LARGE AMOUNTS OF WATER/SALINE FOR 30-60 MINS. COVER
W/STERIL BANDAGES.(SEE SUPP

Flash Point:NON-FLAMMABLE
Extinguishing Media:DRY CHEMICAL/CO2/WATER SPRAY/FOG/REGULAR FOAM.
LARGE FIRES: WATER SPRAY/FOG/REGULAR FOAM. USE AGENTS SUITABLE FOR
FIRE.
Fire Fighting Procedures:MOVE CONTAINER FROM FIRE AREA SAFELY. AVOID
BREATHING CORROSIVE VAPORS. KEEP UPWIND. WEAR SCBA W/A FULL
FACEPIECE OPERATED IN PRESSURE DEMAND MODE.
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO
HEAT/FLAME.

Spill Release Procedures:DON'T TOUCH MATERIAL. STOP LEAK SAFELY. SMALL:
TAKE UP W/SAND/ABSORBENT MATERIAL & PLACE INTO CONTAINERS W/A CLEAN
SHOVEL & COVER FOR LATER DISPOSAL. MOVE CONTAINERS FROM AREA.
LARGE: DIKE & EVACUATE AREA. ISOLATE HAZARD AREA & DENY ENTRY.

Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE
SUBSTANCES. PROTECT FROM PHYSICAL DAMAGE. STORE IN A DRY LOCATION.
DON'T STORE ADJACENT TO ACIDS/ALKALIS.
Other Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER. STORE IN A COOL,
DRY, VENTILATED AREA. MAY BURN BUT DOESN'T IGNITE READILY. KEEP
AWAY FROM FOOD.

Respiratory Protection:ANY DUST & MIST RESPIRATOR, SUPPLIED AIR
RESPIRATOR, SCBA, AIR PURIFYING RESPIRATOR W/A DUST & MIST FILTER,
SCBA W/A FULL FACEPIECE, SUPPLIED AIR RESPIRATOR W/A FULL
FACEPIECE, AIR PURIFYING, FULL-FAC EPIECE RESPIRATOR W/A
PARTICULATE FILTER
Ventilation:LOCAL EXHAUST
Protective Gloves:REQUIRED
Eye Protection:SPLASH-PROOF SAFETY GOGGLES & FACESHIELD
Other Protective Equipment:DUST RESISTANT SAFETY GOGGLES, EYE WASH
FOUNTAIN & SHOWER, PROTECTIVE IMPERVIOUS CLOTHING & EQUIPMENT.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
PH:7.4 SATURATED SOLUTION. FIRST AID CONT'D: INGESTION: IF CONSCIOUS,
GIVE SOLUBLE CALCIUM IN ANY FORM; MILK, CALCIUM GLUCONATE/CALCIUM
SOLUTION. GIVE 200 ML OF WATER & REMOVE FLUORIDE FROM THE INTEST
INE. TREATMENT SHOULD BE GIVEN BY QUALIFIED MEDICAL PERSONNEL.
OBTAIN MEDICAL ATTENTION IN ALL CASES.

Boiling Pt:B.P. Text:3083-3099F
Melt/Freeze Pt:M.P/F.P Text:1819F
Vapor Density:1.4
Spec Gravity:2.78
pH:(SUPP)
Solubility in Water:4.3%
Appearance and Odor:ODORLESS, COLORLESS WHITE TETRAGONAL
CRYSTALS/POWDER

Stability Indicator/Materials to Avoid:YES
ACIDS, ALKALIES, ALUMINUM, GLASS, STRONG OXIDIZERS.
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME.
Hazardous Decomposition Products:TOXIC FUMES OF FLUORIDES & SODIUM
OXIDE.

Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS. POISONOUS MATERIAL UN1690.

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particular situation.